(N 1 E,N 2 E)-N 1,N 2-Bis(4-hex­yloxy-3-methoxy­benzyl­idene)ethane-1,2-diamine

نویسندگان

  • Anju Paul
  • Sherin Susan Punnoose
  • N. L. Mary
  • T. Narasimhaswamy
  • V. Ramkumar
چکیده

The title compound, C(30)H(44)N(2)O(4), was obtained from the dimerization of 4-hexyl-oxyvanillin with ethyl-enediamine in 95% methanol solution. It adopts a trans configuration with respect to the C=N bond and possesses a crystallographically imposed centre of symmetry.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Glycosylated tetrahydrosalens as multifunctional molecules for Alzheimer's therapy.

The tetrahydrosalens N,N'-bis(2-hydroxybenzyl)-ethane-1,2-diamine ((2)(1)), N,N'-bis(2-hydroxybenzyl)-(-)-1,2-cyclohexane-(1R,2R)-diamine ((2)(2)), N,N'-bis(2-hydroxybenzyl)-N,N'-dimethyl-ethane-1,2-diamine ((2)(3)), N,N'-bis(2-hydroxybenzyl)-N,N'-dibenzyl-ethane-1,2-diamine ((2)(4)), and N,N'-bis(2-(4-tert-butyl)hydroxybenzyl)-ethane-1,2-diamine ((2)(5)), as well as their prodrug glycosylated ...

متن کامل

{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ4 N,N′,N′′,N′′′}(thio­cyanato-κN)zinc(II) perchlorate

In the title compound, [Zn(NCS)(C(16)H(18)N(4))]ClO(4), the Zn(II) atom is five-coordinated by four N atoms of the Schiff base ligand N,N'-bis-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine in the basal plane, and by the N atom of a thio-cyanate ligand at the apical position, forming a distorted square-pyramidal geometry. The r.m.s. deviation from a plane through the four N atoms of the Schiff b...

متن کامل

[μ-N,N′-Bis(2-amino­eth­yl)ethane-1,2-diamine-κ4 N 1,N 1′:N 2,N 2′]bis­{[N,N′-bis­(2-amino­eth­yl)ethane-1,2-diamine-κ4 N,N′,N′′,N′′′]cadmium} tetra­kis­(perchlorate)

The centrosymmetric dinuclear cadmium title complex, [Cd(2)(C(6)H(18)N(4))(3)](ClO(4))(4), was obtained by the reaction of N,N'-bis-(2-amino-eth-yl)ethane-1,2-diamine (trien) with Cd(NO(3))(2)·4H(2)O and sodium perchlorate in methanol. The Cd(II) cation is coordinated by four N atoms of a non-bridging trien ligand and by two N atoms of a bridging trien ligand in a slightly distorted octa-hedral...

متن کامل

{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ4 N,N′,N′′,N′′′}bis­(trifluoro­methane­sulfanato-κO)copper(II)

A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetra-dentate Schiff base, N,N'-bis-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine. The copper centre assumes a tetra-gonally distorted pseudo-octa-hedral geometry with the O atoms of two trifluoro-methane-sulfonate anions coordinated weakly in the axial positions. The Cu-N distances l...

متن کامل

Synthesis of ruthenium(II) complexes of tetradentate bis(N-pyridylimidazolylidenyl)methane and their reactivities towards N- donors.

A family of hexa-coordinated ruthenium(II) complexes of bis(N-pyridylimidazolylidenyl)methane (L) were prepared and structurally characterized. Carbene transfer reactions of [Ru(p-cymene)Cl(2)](2), [Ru(CO)(2)Cl(2)](n) and RuHCl(CO)(PPh(3))(3) with silver-NHC complexes in situ generated from [H(2)L](PF(6))(2) and Ag(2)O afforded [RuL(CH(3)CN)(2)](PF(6))(2) (1), [Ru(2)L(p-cymene)(2)Cl(2)](PF(6))(...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010